We obtain exact solutions for kinks in φ 8 , φ 10 and φ 12 field theories with degenerate minima, which can describe a second-order phase transition followed by a first-order one, a succession of two first-order phase transitions and a second-order phase transition followed by two first-order phase transitions, respectively. Such phase transitions are known to occur in ferroelastic and ferroelectric crystals and in meson physics. In particular, we find that the higher-order field theories have kink solutions with algebraically-decaying tails and also asymmetric cases with mixed exponentialalgebraic tail decay, unlike the lower-order φ 4 and φ 6 theories. Additionally, we construct distinct kinks with equal energies in all three field theories considered, and we show the co-existence of up to three distinct kinks (for a φ 12 potential with six degenerate minima). We also summarize phonon dispersion relations for these systems, showing that the higher-order field theories have specific cases in which only nonlinear phonons are allowed. For the φ 10 field theory, which is a quasi-exactly solvable (QES) model akin to φ 6 , we are also able to obtain three analytical solutions for the classical free energy as well as the probability distribution function in the thermodynamic limit.