1987
DOI: 10.1007/bf01913975
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Statistical evaluation of non-isothermal decomposition kinetics analysis methods for AIBN

Abstract: Decomposition kinetics parameters were obtained from non-isothermal DSC data for the decomposition of AIBN by two data analysis methods. A statistical evaluation of the results showed that there was no difference between the results obtained by each data analysis method and that the heating rate did not significantly affect the values of the kinetics parameters. Both data analysis methods isolate the order of reaction, n, the activation energy, E, and the Arrhenius factor, A, from a single non-isothermal scan … Show more

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Cited by 8 publications
(1 citation statement)
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References 21 publications
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“…DMTA is particularly useful for the characterization of individual networks in interpenetrating polymer networks (IPNs) 18, 19. Provder and coworkers20–22 deduced that increased chemical heterogeneity (the appearance of shoulders and doublets in the tan δ curves) would result in an increase in the impact strength. Sluszny et al23 and Takeichi et al24 also used thermal methods, including dynamic viscoelastic measurements, to characterize novel semi‐IPNs and polymer blends.…”
Section: Introductionmentioning
confidence: 99%
“…DMTA is particularly useful for the characterization of individual networks in interpenetrating polymer networks (IPNs) 18, 19. Provder and coworkers20–22 deduced that increased chemical heterogeneity (the appearance of shoulders and doublets in the tan δ curves) would result in an increase in the impact strength. Sluszny et al23 and Takeichi et al24 also used thermal methods, including dynamic viscoelastic measurements, to characterize novel semi‐IPNs and polymer blends.…”
Section: Introductionmentioning
confidence: 99%