In this chapter, we explore the possibility for spin systems to develop a type of order that breaks the O(3) spin symmetry but does not have a magnetic moment. Such ordering is usually referred to as multipolar or nematic, with quadrupolar being the simplest example. These phases have been found in S D 1 Heisenberg models extended with biquadratic exchange, in certain S D 1=2 Heisenberg models with both ferromagnetic and antiferromagnetic exchange couplings, and in models with cyclic ring-exchange terms. We present theoretical and numerical methods which can be used to understand and characterize quadrupolar and nematic phases. While quadrupolar/nematic ordering is well documented in model systems, it has not yet been identified unambiguously in real materials, although there exist some promising candidates which we also review.
Introduction and MaterialsMagnetism and spins are usually thought to be inseparable. It is the quantum mechanical spin of individual electrons which, through Hund's rules, forms the moment of a magnetic ion. When these magnetic ions interact, the spins usually order in the ground state, and the individual spins are oriented in a given direction in spin space. Such a state breaks spontaneously both spin-rotation and time-reversal symmetries. An essential property of quantum mechanical systems is the possibility of discovering phases which do not carry a magnetic moment and do not break timereversal symmetry. One paradigm is that spin-1/2 entities may pair into singlets, realizing valence-bond phases of different kinds [1] -in such a quantum paramagnetic phase, neither the spin-rotation nor the time-reversal symmetry is broken, as discussed in Chap. 2 by Lhuillier and Misguich. One might ask whether yet more exotic possibilities exist, for example a phase without magnetic order, but which nevertheless breaks spin-rotation symmetry. This chapter explores such a situation.In the following, we call a spin nematic any state that has no magnetic order, i.e. hS i i D 0, but still breaks the spin rotational symmetry, by virtue of a more complicated order parameter. The simplest such example is onsite quadrupolar order, where 331