State-of-the-art progress in tracking plasmon-mediated photoredox catalysis

Abstract

Metal nanocrystals (NCs), particularly for plasmonic metal NCs with specific morphology and size, can strongly interact with ultraviolet-visible or even near-infrared photons to generate energetic charge carriers, localized heating, and electric field enhancement. These unique properties offer a promising opportunity for maneuvering solar-to-chemical energy conversion through different mechanisms. As distinct from previous works, in this review, recent advances of various characterization techniques in probing and monitoring the photophysical/photochemical processes, as well as the reaction mechanisms of plasmon-mediated photoredox catalysis are thoroughly summarized. Understanding how to distinguish and track these reaction mechanisms would furnish basic guidelines to design next-generation photocatalysts for plasmon-enhanced catalysis.