Standard molar enthalpies of formation of some trichloroanilines by rotating-bomb calorimetry

Standard molar enthalpies of formation of 2-chloroquinoline, 4-chloroquinoline, 6-chloroquinoline and 4,7-dichloroquinoline by rotating-bomb calorimetry

“…Both the apparatus and the operating technique have been described [22][23][24][25][26][27] so only a brief description will be given here. The bomb, with an internal volume of 0.258 dm 3 , is of stainless steel lined with platinum, and the internal fittings are machined from platinum.…”

Combined experimental and computational thermochemistry of isomers of chloronitroanilines

“…The present work is part of our broad interest on the thermochemistry of halogenated anilines, for which we have studied fluoroanilines [6,7], chloroanilines [8][9][10][11], bromoanilines [12], and iodoanilines [13]. Recently, two isomers of chloronitroaniline, 2-chloro-4-nitroaniline and 2-chloro-5-nitroaniline, were the object of a detailed experimental and computational study [14].…”

Experimental thermochemical study of 2,5- and 2,6-dichloro-4-nitroanilines

“…The present work is a contribution to the thermochemical investigation of halogenated anilines and nitroanilines carried out by the Molecular Energetics Research Group of the University of Porto, following the studies of fluoroanilines [6,7], chloroanilines [8][9][10][11], bromoanilines [12], iodoanilines [13] and monochloronitroanilines [14,15]. This paper reports the standard (p°= 0.1 MPa) molar enthalpies of formation, of 2,5-and 2,6-dichloro-4-nitroanilines, in the crystalline phase, at T = 298.15 K, derived from the standard massic energies of combustion, of those two compounds, in oxygen, at the same temperature, measured by rotating-bomb combustion calorimetry.…”