Standard molar enthalpies of formation, vapour pressures, and enthalpies of sublimation of 2-chloro-4-nitroaniline and 2-chloro-5-nitroaniline

Combined experimental and computational thermochemistry of isomers of chloronitroanilines

“…A detailed description of the apparatus and the general operating technique may be found in the literature [14,19,20].…”

“…Recently, two isomers of chloronitroaniline, 2-chloro-4-nitroaniline and 2-chloro-5-nitroaniline, were the object of a detailed experimental and computational study [14]. In this paper we report the experimental thermochemical study of 4-chloro-3-nitroaniline and 5-chloro-2-nitroaniline, and the computational thermochemistry study of all the isomers of chloronitroaniline.…”

Standard molar enthalpies of formation of 2-chloroquinoline, 4-chloroquinoline, 6-chloroquinoline and 4,7-dichloroquinoline by rotating-bomb calorimetry

“…Both the apparatus and the operating technique have been described [22][23][24][25][26][27] so only a brief description will be given here. The bomb, with an internal volume of 0.258 dm 3 , is of stainless steel lined with platinum, and the internal fittings are machined from platinum.…”

Thermochemical study of some chloro and bromo alkyl substituted phthalimides: Structural–energetic correlations

“…Both the apparatus and the operating technique have been described [39][40][41][42][43][44] so only a brief description will be given here. The twin valve bomb, with an internal volume of 0.258 dm 3 and wall thickness of 1 cm, is made of stainless steel, internally lined with platinum, with all the internal fittings entirely machined from platinum.…”

“…Hence, the accuracy of the calorimeter has been checked in our laboratory by measuring the energy of combustion of 4-chlorobenzoic acid, in the pellet form, in oxygen at p = 3.04 MPa, in the presence of an aqueous solution of As 2 O 3 in the bomb. The results obtained for the enthalpy of combustion of 4-chlorobenzoic acid, D c H m ¼ Àð3064:5 AE 1:2Þ kJ Á mol À1 [41] and D c H m ¼ Àð3063:92 AE 0:91Þ kJ Á mol À1 [44], are in very good agreement with the recommended value, D c H m ¼ Àð3063:48 AE 0:23Þ kJ Á mol À1 [36]. Values of D c H m refer to the reaction with HCl AE 600H 2 O(l) as the chlorine containing product in the final state.…”