A generalized set of conservative equations for simulating the flowfield in a hypersonic weakly ionized gas flows is presented. Additional numerical and physical complexities associated with the plasma state are identified and discussed, including the influence of external and space charge fields and the nonequilibrium coupling of reactive and nonreactive collisions. A restricted set of equations is then employed to simulate and analyze the flowfield of an air plasma generated by associative ionization. With use of a seven-species air model, details of the plasma flowfields are presented and compared with available experiments. Refined estimates of dissociation products, which are the precursors to the ionization reaction, are obtained. Specific attention is given to limiting forms of the electron diffusion coefficient and the influence of vibration-dissociation coupling. Details of the chemical reactions in the flowfield influencing the elastic and inelastic collisional energy transfer are reported to highlight the more important species and reaction mechanisms.
Nomenclaturefunction of space and time, V/m E e = translational energy of electrons per unit volume, J/m 3 e = total energy per unit mass, J/kg F ela,s = force per unit volume due to elastic collisions, N/m 3 F ele,s = force per unit volume due to electric field, N/m 3 F inela,s = force per unit volume due to inelastic collisions, N/m 3 h 0 = enthalpy of formation, J/kg k = Boltzmann constant, 1.3807 × 10 −23 J/K L = characteristic length, m M = Mach number M = molecular weight, kg/mole M e = electron mass, 9.1094 × 10 −31 kg m = mass, kg N = number density, number/m 3 N = Avogadro's number, 6.02252 × 10 23 /mole p = pressure, N/m 2 Q = energy exchange between modes, J/m 3 s Q rad = radiation heat loss term, J/m 3 s q = charge, C q j = heat flux vector, W/m 2 T = translational temperature, K T eff = effective temperature at which dissociation or ionization reaction is considered, K T v = vibrational temperature, K u j = mass-averaged velocity component of mixture fluid in three dimensions, where j is 1-3 u j s = average or mean velocity of species s in three dimensions, where j is 1-3 m/s V = random or peculiar velocity or diffusion velocity, m/s v j s = velocity of species s in three dimensions, where j is 1-3 m/s X = mole fraction x j = position vector in three dimensions, where j is 1-3 m Z s = ionic valency, −1 for electrons, 1 for single-ionized positive ions = electron or ion flux density, number/m 2 · s ε = elementary electronic charge, 1.6022 × 10 −19 C 0 = permittivity of free space, 8.8542 × 10 −12 F/m η = thermal conductivity coefficient, W/mK d = characteristic temperature of dissociation, K v = characteristic temperature of vibration, K ν = collision frequency, Hz ν * er = effective collision frequency of electrons with diatomic molecules (heavy particles), Hz ρ = total density, kg/m 3 ρ n = state density in the nth vibrational level, kg/m 3 σ = collision cross section, m 2 τ = relaxation time, s τ i j = viscous shear stress, N/m 2 ω pe = el...