2020
DOI: 10.1002/adma.201908311
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Stacking‐Order‐Driven Optical Properties and Carrier Dynamics in ReS2

Abstract: textTwo distinct stacking orders in ReS2 are identified without ambiguity and their influence on vibrational, optical properties and carrier dynamics are investigated. With atomic resolution scanning transmission electron microscopy (STEM), two stacking orders are determined as AA stacking with negligible displacement across layers, and AB stacking with about a one-Received: ((will be filled in by the editorial staff)) Revised: ((will be filled in by the editorial staff)) Published online: ((will be filled in … Show more

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Cited by 51 publications
(89 citation statements)
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“…In particular, the low frequency Raman spectra can also be used to judge the stacking order in ReX 2 crystal, as the interlayer phonon modes are sensitive to lattice coupling between the ReX 2 layers. [68][69]72] Additionally, from the aspect of force constants per unit (k S ) of low frequency modes, the k S of ReS 2 and ReSe 2 are 17.1 and 17.1 × 10 18 N m −3 , much smaller than the force constant of other materials (MoS 2 : 25 × 10 18 N m −3 , MoTe 2 : 34 × 10 18 N m −3 , and PtSe 2 : 46 × 10 18 N m −3 , etc.). [55,67,70,73] Above results indicate that ReX 2 has a rather weak interlayer coupling.…”
Section: Optical and Vibration Propertiesmentioning
confidence: 99%
“…In particular, the low frequency Raman spectra can also be used to judge the stacking order in ReX 2 crystal, as the interlayer phonon modes are sensitive to lattice coupling between the ReX 2 layers. [68][69]72] Additionally, from the aspect of force constants per unit (k S ) of low frequency modes, the k S of ReS 2 and ReSe 2 are 17.1 and 17.1 × 10 18 N m −3 , much smaller than the force constant of other materials (MoS 2 : 25 × 10 18 N m −3 , MoTe 2 : 34 × 10 18 N m −3 , and PtSe 2 : 46 × 10 18 N m −3 , etc.). [55,67,70,73] Above results indicate that ReX 2 has a rather weak interlayer coupling.…”
Section: Optical and Vibration Propertiesmentioning
confidence: 99%
“…Previous reports suggested three (two) stacking configurations for bilayer (bulk) ReS 2 [19,54]. Accordingly for our bilayer sample, we considered stacking configurations (labeled stacking configuration 1, 2, 3 in Table-I) from Ref.…”
Section: B Theoretical Calculationsmentioning
confidence: 99%
“…. In addition, we have considered the fourth stacking configuration of bilayer ReS 2 with the two monolayers on top of each other, terming it as AA stacking (labeled stacking 0) similar to Ref 54…”
mentioning
confidence: 99%
“…Based on the opened bandgap, Deng et al achieved strong mid-infrared detection in the 1.81° twisted bilayer graphene [139]. Recently, the relationships between Raman spectrum and the stacked manner have been broadly investigated [140][141][142][143]. Carozo et al introduced a double-resonance model in twisted graphene [144].…”
Section: Raman Spectroscopymentioning
confidence: 99%