Stable thiolate adducts of Rh2(OAc)4– assembly of hexametallic Ni4Rh2complexes

This article covers 50 years of coordination chemistry of transition metal complexes and metal-sulfur aggregates involving thiolate-incorporating ligands by reviewing selected examples. The studies in the coordination chemistry of sulfur-rich ligands have been undoubtedly triggered and fed by the concomitant development of bioinorganic chemistry, particularly of iron-sulfur enzymes. The review is broken down in five sections, which examine complexes of increasing nuclearity, including binuclear complexes based on compartmental macrocyclic ligands. We show also how ligand engineering has allowed the researchers in the field to control the nuclearity of the complexes, which was a particularly difficult task for sulfurbased ligands, as thiolates show a strong tendency to coordinate to more than one metal cation at once.

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Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands

Taut

Chambron

Kersting

2023

Eur J Inorg Chem

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Stable thiolate adducts of Rh₂(OAc)₄– assembly of hexametallic Ni₄Rh₂complexes

Abstract: Thiolate adducts of dirhodium(II) tetraacetate have proven difficult to prepare. We isolated a stable, paramagnetic Ni4Rh2 adduct containing Ni-based metallothiolates bound in axial positions of the Rh24+ core. The adduct...

Cited by 1 publication

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Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands

Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands

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