“…Because the d 13 C value of organic matter is distinct from that of methane and there is little carbon isotopic fractionation during the transformation from organic matter and methane to DIC (Gieskes et al, 2005;Roberts et al, 2010), the carbon isotopic composition of the DIC pool is a critical parameter for fingerprinting the carbon source and understanding the carbon biogeochemical cycling (Chen et al, 2004(Chen et al, , 2010Feng and Roberts, 2010;Yang et al, 2008 (Harrison and Thode, 1958). As a result, the sulfur isotopic compositions of dissolved sulfate in pore waters have been widely used as an indicator of the occurrence of bacterial sulfate reduction (Böttcher et al, 2000;Feng and Roberts, 2011;Jørgensen, 1979). In addition, sulfate-reducing bacteria are able to generate high sulfur isotope fractionation; the maximum sulfur isotope fractionation between sulfate and sulfide was up to 72& (Wortmann et al, 2001).…”