Abstract:We report the synthesis of palladium nanoparticles encapsulated N-doped carbon nanofibers derived from environmentally benign chitosan. Palladium salt was incorporated into the chitosan/sodium polyacrylate composite nanofibers by electrospinning, followed by carbonization under argon atmosphere to prepare palladium encapsulated mesoporous carbon nanofibers (Pd@Carbon). SEM
“…The catalytic system composed of DMAB can also catalyze the polymerization of olefin and unsaturated carboxylate in place of the MAO. The invention in [ 78 ] discloses a novel polymer preparation method. Olefin and unsaturated carboxylate react in the presence of the catalyst composition, which may include DMAB, making the polymerization process more efficient.…”
Section: Research Progress Of Ammonium Tetrakis(pentafluorophenyl)boratementioning
Metallocene catalysts have attracted much attention from academia and industry for their excellent catalytic activity in the field of olefin polymerization. Cocatalysts play a key role in metallocene catalytic systems, which can not only affect the overall catalytic activity, but also have an obvious influence on the structure and properties of the polymer. Although methylaluminoxane (MAO) is currently the most widely used cocatalyst, its price increases the production cost of polyolefin materials. Ammonium tetrakis(pentafluorophenyl)borate has shown excellent performance in polymerization, being one of the best substitutes for the traditional cocatalyst MAO. Compared with the main catalyst, whose composition and structure are relatively complex, the research on cocatalyst is very limited. This review mainly introduces the research history, preparation methods, and application progress in polymerization of ammonium tetrakis(pentafluorophenyl)borate, deepening our understanding of the role of cocatalyst in polymerization, with the hope of inspiring brand-new thinking on improving and enhancing the overall performance of catalyst systems.
“…The catalytic system composed of DMAB can also catalyze the polymerization of olefin and unsaturated carboxylate in place of the MAO. The invention in [ 78 ] discloses a novel polymer preparation method. Olefin and unsaturated carboxylate react in the presence of the catalyst composition, which may include DMAB, making the polymerization process more efficient.…”
Section: Research Progress Of Ammonium Tetrakis(pentafluorophenyl)boratementioning
Metallocene catalysts have attracted much attention from academia and industry for their excellent catalytic activity in the field of olefin polymerization. Cocatalysts play a key role in metallocene catalytic systems, which can not only affect the overall catalytic activity, but also have an obvious influence on the structure and properties of the polymer. Although methylaluminoxane (MAO) is currently the most widely used cocatalyst, its price increases the production cost of polyolefin materials. Ammonium tetrakis(pentafluorophenyl)borate has shown excellent performance in polymerization, being one of the best substitutes for the traditional cocatalyst MAO. Compared with the main catalyst, whose composition and structure are relatively complex, the research on cocatalyst is very limited. This review mainly introduces the research history, preparation methods, and application progress in polymerization of ammonium tetrakis(pentafluorophenyl)borate, deepening our understanding of the role of cocatalyst in polymerization, with the hope of inspiring brand-new thinking on improving and enhancing the overall performance of catalyst systems.
“…36 A family of noble metal catalysts known as Pd has a distinctive structure and several uses. 33,[45][46][47][48][49][50] Over time, various palladium-based catalytic materials have been created to attain high catalytic potential to reduce nitro compounds. 8,[34][35][36][37][51][52][53][54][55] Heavy metal contamination of water is a major ecological concern, especially in industrial wastewater, where Cr(VI) is a major pollutant.…”
Section: Introductionmentioning
confidence: 99%
“…At present, researchers have developed a range of nanocatalysts utilizing noble metals to reduce nitro compounds, such as Pd, Pt, Au, and Ru 36 . A family of noble metal catalysts known as Pd has a distinctive structure and several uses 33,45–50 . Over time, various palladium‐based catalytic materials have been created to attain high catalytic potential to reduce nitro compounds 8,34–37,51–55 …”
This study reports the synthesis and characterization of an environmentally friendly, cost‐effective, and sustainable Pd‐heterogeneous catalyst anchored on superparamagnetic silica‐coated iron oxide. The synthesized Pd‐SB/MNP nanomagnetic catalyst was extensively characterized using Fourier transform infrared (FTIR), inductively coupled plasma optical emission spectroscopy (ICP‐OES), X‐ray photoelectron spectroscopy (XPS), X‐ray diffraction (XRD), energy‐dispersive spectrometry (EDS), vibrating sample magnetometry (VSM), field emission scanning electron microscopy (FE‐SEM), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET), and high‐resolution transmission electron microscopy (HR‐TEM). The Pd‐SB/MNP catalyst showed remarkable efficiency in catalyzing the reduction of nitroarene and Cr(VI) under mild reaction conditions using an eco‐friendly solvent. The catalyst exhibits facile recovery through external magnetization, enabling its efficient recycling and reutilization for at least 10 cycles while demonstrating minimal Pd loss, as confirmed by rigorous hot filtration testing and ICP‐OES analysis. These results comply with the industry's prescribed thresholds for permissible levels of residual metallic content. The results suggest that the synthesized Pd‐SB/MNP catalyst holds great potential for various industrial applications.
A novel and sustainable tandem‐catalysis system for asymmetric synthesis is disclosed, which is fabricated by bio‐inspired self‐assembly of artificial arthropod exoskeletons (AAEs) or artificial fungi cell walls (AFCWs) containing two different types of catalysts (enzyme and metal nanoparticles). The heterogeneous integrated enzyme/metal nanoparticle AAE/AFCW systems, which contain chitosan as the main structural component, co‐catalyze dynamic kinetic resolution of primary amines via a tandem racemization/enantioselective amidation reaction process to give the corresponding amides in high yields and excellent ee. The heterogeneous AAE/AFCW systems display successful heterogeneous synergistic catalysis at the surfaces since they can catalyze multiple reaction cycles without metal leaching. The use of natural‐based and biocompatible structural components makes the AAE/AFCW systems fully biodegradable and renewable, thus fulfilling important green chemistry requirements.
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