Stabilization of CeGe$_3$ with Ti and O featuring tetravalent Ce ions: (Ce$_{0.85}$Ti$_{0.15}$)Ge$_3$O$_{0.5}$
Hanshang Jin,
Jackson Badger,
Peter Klavins
et al.
Abstract:Sub-oxides with the anti-perovskite structure constitute a large part of the interstitial stabilized compounds with novel chemical and physical properties, especially in the systems containing rare earth elements and/or early transition metal elements. A new sub-oxide compound, (Ce 0.85 Ti 0.15 )Ge 3 O 0.5 , is synthesized by flux growth. The compound crystallizes in a cubic structure which can be considered as an ordered vacancy variant of anti-perovskite-structure or an ordered interstitial variant of the Cu… Show more
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