1998
DOI: 10.1063/1.475513
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Stability of H, D, N14, and N15 atoms in solid ammonia above 100 K

Abstract: The measurements reported below quantify the stability and decay of hydrogen, deuterium, and nitrogen atoms in frozen ammonia above 100 K. The decay of H atoms is observed on a time scale of minutes in the range of 100-110 K and follows first-order kinetics. Analogous decays of D and N atoms are observed in the ranges 105-120 and 140-160 K, respectively. Activation energies for the decay processes range from 0.1 to 0.4 eV.

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Cited by 11 publications
(3 citation statements)
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“…• H 2 and atomic H, so once they are produced it is impractical to remove them without the loss of the wanted, "good" centers from the material [95].…”
Section: End Of Lifementioning
confidence: 99%
“…• H 2 and atomic H, so once they are produced it is impractical to remove them without the loss of the wanted, "good" centers from the material [95].…”
Section: End Of Lifementioning
confidence: 99%
“…This process is called annealing the target. While anneals allow polarization recovery for a given ammonia sample, the sample still have a limited lifetime due to creation of bad radicals from accumulated radiation damage and thus need to be replaced periodically [111].…”
Section: Setupmentioning
confidence: 99%
“…Radicals such as hydrazine, N can be formed from radicals produced in the beam, such as N• when the material is heated during an anneal. These hydrazine radicals recombine at higher temperatures than N and atomic H, so once they are produced it is impractical to remove them without the loss of the wanted, "good" centers from the material[95].…”
mentioning
confidence: 99%