Stability of Cobalt(II) Complexes with Glycinate Ion as a Function of Water–Dimethyl Sulfoxide Solvent Composition

Quantum-chemical calculations of the structure of the molecular forms of glycine and glycylglycine and conjugate ionic forms have been performed. Our own and published data on the thermodynamic characteristics of the reactions of acid–base interactions of glycine and glycylglycine in aqueous organic solutions are summarized, and the influence of the composition of mixed solvents on the acid dissociation constant of the amide group in the copper(II) peptide complex is considered.

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Stability of Cobalt(II) Complexes with Glycinate Ion as a Function of Water–Dimethyl Sulfoxide Solvent Composition

Cited by 3 publications

References 36 publications

Constants of Stability of Cobalt(II) Complexes with Glycylglycinate Ions in Aqueous Acetone Solutions

Constants of Stability of Cobalt(II) Complexes with Glycylglycinate Ions in Aqueous Acetone Solutions

Protolytic Equilibrium of Glycine and Glycylglycine: Structure of Ionic Forms and Solvent Effect on the Thermodynamic Parameters of Processes

Protolytic Equilibrium of Glycine and Glycylglycine: Structure of Ionic Forms and Solvent Effect on the Thermodynamic Parameters of Processes

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