Stability Enhancement of Laser-Scribed Reduced Graphene Oxide Electrodes Functionalized by Iron Oxide/Reduced Graphene Oxide Nanocomposites for Nitrite Sensors

Brahem, Amina; Al‐Hamry, Ammar; Gross, Marcos A.; Paterno, Leonardo G.; Ali, Mounir Ben; Kanoun, Olfa

doi:10.3390/jcs6080221

Cited by 12 publications

(8 citation statements)

References 39 publications

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“…In addition, the changes are visible in the 2D region above 2500 cm −1 , confirming effective reduction. This conclusion is in agreement with previous reports [39,54]. The change of color from brownish to black after reduction is observable in optical and microscope images in Figures 1 and S1.…”

Section: Physical Characterizationsupporting

confidence: 94%

“…In addition, the changes are visible in the 2D region above 2500 cm −1 , confirming effective reduction. This conclusion is in agreement with previous reports [39,54]. The change of color from brownish to black after reduction is Raman spectra of GO and GO/MWNT composites (Figure 2b) show high similarity, indicating that the GO component dominates the spectra.…”

Section: Physical Characterizationsupporting

confidence: 93%

“…Combined with direct laser writing, GO structured sensors have the advantages of high performance, low cost, miniaturization, patterning, low-temperature operation, nontoxic, and no-photomasks [37]. Apart from that, laser-scribed rGO also shows suitable conductivity and chemical stability, allowing it to be utilized in humidity sensing [38,39]. Fast and highly sensitive graphene-based humidity sensors produced in a single-step laser fabrication have been reported [40][41][42][43] as films with all-graphene interdigitated rGO-GO-rGO structure in a wide humidity range of 6.3% to RH 100% and response/recovery in the range of several seconds, compared among the best performing materials.…”

Section: Introductionmentioning

confidence: 99%

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Ultra-Sensitive and Fast Humidity Sensors Based on Direct Laser-Scribed Graphene Oxide/Carbon Nanotubes Composites

Al‐Hamry

Chen

et al. 2023

Nanomaterials

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In this paper, the relative humidity sensor properties of graphene oxide (GO) and graphene oxide/multiwalled nanotubes (GO/MWNTs) composites have been investigated. Composite sensors were fabricated by direct laser scribing and characterized using UV-vis-NIR, Raman, Fourier transform infrared, and X-ray photoemission spectroscopies, electron scanning microscopy coupled with energy-dispersive X-ray analysis, and impedance spectroscopy (IS). These methods confirm the composite homogeneity and laser reduction of GO/MWNT with dominant GO characteristics, while ISresults analysis reveals the circuit model for rGO-GO-rGO structure and the effect of MWNT on the sensor properties. Although direct laser scribing of GO-based humidity sensor shows an outstanding response (|ΔZ|/|Z| up to 638,800%), a lack of stability and repeatability has been observed. GO/MWNT-based humidity sensors are more conductive than GO sensors and relatively less sensitive (|ΔZ|/|Z| = 163,000%). However, they are more stable in harsh humid conditions, repeatable, and reproducible even after several years of shelf-life. In addition, they have fast response/recovery times of 10.7 s and 9.3 s and an ultra-fast response time of 61 ms when abrupt humidification/dehumidification is applied by respiration. All carbon-based sensors’ overall properties confirm the advantage of introducing the GO/MWNT hybrid and laser direct writing to produce stable structures and sensors.

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Section: Physical Characterizationsupporting

confidence: 94%

“…In addition, the changes are visible in the 2D region above 2500 cm −1 , confirming effective reduction. This conclusion is in agreement with previous reports [39,54]. The change of color from brownish to black after reduction is Raman spectra of GO and GO/MWNT composites (Figure 2b) show high similarity, indicating that the GO component dominates the spectra.…”

Section: Physical Characterizationsupporting

confidence: 93%

Section: Introductionmentioning

confidence: 99%

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Ultra-Sensitive and Fast Humidity Sensors Based on Direct Laser-Scribed Graphene Oxide/Carbon Nanotubes Composites

Al‐Hamry

Chen

et al. 2023

Nanomaterials

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“…Extensive research has been conducted on the electrochemical detection of nitrite by modifying the working electrode with different nanomaterials and composites owing to the high oxidation potential required for the oxidation of nitrite on bare electrodes [ 20 ]. Surfaces based on carbon nanomaterials such as carbon nanotubes [ 21 , 22 ], graphene [ 23 ], and graphene oxide [ 24 , 25 ] have been employed for the detection of nitrite. In addition, metallic and bimetallic nanoparticles, including silver [ 26 ], gold (Au) [ 27 ], and copper [ 28 ], have also been used for the detection of nitrite.…”

Section: Existing Solutions In the Literaturementioning

confidence: 99%

Towards Embedded Electrochemical Sensors for On-Site Nitrite Detection by Gold Nanoparticles Modified Screen Printed Carbon Electrodes

Adiraju

Munjal

Viehweger

et al. 2023

Sensors

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The transition of electrochemical sensors from lab-based measurements to real-time analysis requires special attention to different aspects in addition to the classical development of new sensing materials. Several critical challenges need to be addressed including a reproducible fabrication procedure, stability, lifetime, and development of cost-effective sensor electronics. In this paper, we address these aspects exemplarily for a nitrite sensor. An electrochemical sensor has been developed using one-step electrodeposited (Ed) gold nanoparticles (EdAu) for the detection of nitrite in water, which shows a low limit of detection of 0.38 µM and excellent analytical capabilities in groundwater. Experimental investigations with 10 realized sensors show a very high reproducibility enabling mass production. A comprehensive investigation of the sensor drift by calendar and cyclic aging was carried out for 160 cycles to assess the stability of the electrodes. Electrochemical impedance spectroscopy (EIS) shows significant changes with increasing aging inferring the deterioration of the electrode surface. To enable on-site measurements outside the laboratory, a compact and cost-effective wireless potentiostat combining cyclic and square wave voltammetry, and EIS capabilities has been designed and validated. The implemented methodology in this study builds a basis for the development of further on-site distributed electrochemical sensor networks.

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“…Based on above discussion, GO is a good candidate for different sensor applications with facile methods of preparation and coating. With LbL technique, tuned film thickness, sensitivity, stability and adhesion can be obtained [31,34]. Here we present LbL-manufactured PDAC/rGO composite-based sensors, which can be used as temperature, relative humidity, and VOCs sensors, while they also show potential for use in electrochemical sensors of pesticides.…”

Section: Of 18mentioning

confidence: 99%

Layer-by-Layer Deposited Multi-Modal PDAC/rGO Composite-based Sensors

Al‐Hamry¹,

Lu²,

Bai³

et al. 2022

Preprint

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Precise monitoring of different environmental parameters and contaminations during food processing and storage is a key factor for maintaining its safety and nutritional value. Thus, developing reliable, efficient, cost-effective sensor devices for these purposes is of utmost importance. In this paper, we show that Poly-(diallyl-dimethylammonium chloride)/reduced Graphene oxide (PDAC/rGO) films produced by a simple Layer-by-Layer deposition can be effectively used to monitor temperature, relative humidity and the presence of volatile organic compounds as indicators for spoilage odors. At the same time, they show potential for electrochemical detection of organophosphate pesticide dimethoate. By monitoring the resistance/impedance changes during temperature and relative humidity variations or upon the exposure of PDAC/rGO films to methanol, good linear responses were obtained in the temperature range of 10-100 °C, 15-95 % relative humidity, and 35 ppm - 55 ppm of methanol. Moreover, linearity in the electrochemical detection of dimethoate is shown for the concentrations in the order of 102 µmol dm−3. The analytical response to different external stimuli and analytes depends on the number of layers deposited, affecting sensors’ sensitivity, response and recovery time, and long-term stability. The presented results could serve as a starting point for developing advanced multimodal sensor devices and sensor arrays with high potential for analytical applications in food safety and quality monitoring.

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Stability Enhancement of Laser-Scribed Reduced Graphene Oxide Electrodes Functionalized by Iron Oxide/Reduced Graphene Oxide Nanocomposites for Nitrite Sensors

Cited by 12 publications

References 39 publications

Ultra-Sensitive and Fast Humidity Sensors Based on Direct Laser-Scribed Graphene Oxide/Carbon Nanotubes Composites

Ultra-Sensitive and Fast Humidity Sensors Based on Direct Laser-Scribed Graphene Oxide/Carbon Nanotubes Composites

Towards Embedded Electrochemical Sensors for On-Site Nitrite Detection by Gold Nanoparticles Modified Screen Printed Carbon Electrodes

Layer-by-Layer Deposited Multi-Modal PDAC/rGO Composite-based Sensors

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