Stability constants of SnCl2-pyridine N-oxide complexes in acetonitrile

Scott, Paul T.; Kauffman, Jim W.; Rogers, J. W.; Williams, R. J.

doi:10.1016/0022-1902(77)80405-3

Journal of Inorganic and Nuclear Chemistry

1977

DOI: 10.1016/0022-1902(77)80405-3

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Stability constants of SnCl2-pyridine N-oxide complexes in acetonitrile

Paul T. Scott

Jim W. Kauffman

J. W. Rogers

et al.

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1979

1983

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Cited by 5 publications

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“…The plateau current of the lower potential wave is controlled by the formation of the very stable SnC13-species which is only reducible at potentials of the second wave. Stannous chloride was found also to act as a Lewis acid toward various pyridine-N-oxide ligands; forming 1:1 adducts in ACN (5,7,8).…”

mentioning

confidence: 99%

Polarography of Sn(IV) and Ge(IV) Chloride in Acetonitrile

Young¹,

Coles²,

Meux³

et al. 1980

J. Electrochem. Soc.

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Spectrophotometric and polarographic data demonstrate that the normal Sn(IV) and Ge(IV) chlorides are nonelectrolytes in the aprotic solvent acetonitrile. Both form the corresponding hexachloro species in the presence of chloride ion. Sn(IV) chloride is quantitatively converted to the hexachlorostannate ion while Ge(IV) chloride behaves as a weaker Lewis acid and exists in an equilibrium with the hexochloro ion in the presence of excess chloride. Each of the normal metal halides acts as a Lewis acceptor toward a test pyridine‐N‐oxide ligand in acetonitrile. Sn(IV) and Ge(IV) chloride are polarographically reduced in a 4e − step at which the production of the corresponding hexachloro ion, reducible only at higher potentials, controls the plateau current.

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mentioning

confidence: 99%

Polarography of Sn(IV) and Ge(IV) Chloride in Acetonitrile

Young¹,

Coles²,

Meux³

et al. 1980

J. Electrochem. Soc.

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1,10-Phenanthroline N-oxide complexes with Sn(II) and (IV) halides

Owens¹,

Filo²,

Woods³

et al. 1981

Journal of Inorganic and Nuclear Chemistry

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Labile 1,10-phenanthroline N-oxide complexes with tin(II) and (IV) halides

Owens

Filo

Woods

et al. 1980

Inorganica Chimica Acta

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Stability constants of SnCl2-pyridine N-oxide complexes in acetonitrile

Cited by 5 publications

References 8 publications

Polarography of Sn(IV) and Ge(IV) Chloride in Acetonitrile

Polarography of Sn(IV) and Ge(IV) Chloride in Acetonitrile

1,10-Phenanthroline N-oxide complexes with Sn(II) and (IV) halides

Labile 1,10-phenanthroline N-oxide complexes with tin(II) and (IV) halides

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