Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response

Huang, Zhenjun; Su, Xin; Pan, Shilie; Dong, Xiaoyu; Han, Shujuan; Yu, Hongwei; Zhang, Min; Yang, Yun; Cui, Sifang; Yang, Zhihua

doi:10.1016/j.scriptamat.2013.05.031

Cited by 27 publications

(15 citation statements)

References 31 publications

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“…All these properties indicate that K3B6O10X could be a good candidate for second-and third-harmonic generation for laser at 1064 nm [61,62]. Ba3B6O11F2 and Sr3B6O11F2 with (B6O14) 10− Ba3B6O11F2 and Sr3B6O11F2 are isomorphism and crystallize in monoclinic space group P21 [63,64]. Two (B3O8) 3− are linked by sharing the oxygen of (BO4) 5− to form the (B6O14) 10− building block.…”

Section: Borate Crystals Containing the B-o Combinational Groupsmentioning

confidence: 97%

“…In this section, we select Ba3(ZnB5O10)PO4 and Cs2B4SiO9 as the representative examples. Ba3B6O11F2 and Sr3B6O11F2 with (B6O14) 10− Ba3B6O11F2 and Sr3B6O11F2 are isomorphism and crystallize in monoclinic space group P21 [63,64]. Two (B3O8) 3− are linked by sharing the oxygen of (BO4) 5− to form the (B6O14) 10− building block.…”

Section: The Borates Containing B-o Groups and Other Nlo Active Groupsmentioning

confidence: 99%

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Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

et al. 2017

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Abstract:Borates have long been recognized as a very important family of nonlinear optical (NLO) crystals, and have been widely used in the laser frequency-converting technology in ultraviolet (UV) and deep-ultraviolet (DUV) regions. In this work, the borate-based UV and DUV NLO crystals discovered in the recent decade are reviewed, and the structure-property relationship in the representative borate-based UV and DUV NLO crystals is analyzed. It is concluded that the optical properties of these crystals can be well explained directly from the types and spatial arrangements of B-O groups. The deduced mechanism understanding has significant implications for the exploration and design of new borate-based crystals with excellent UV and DUV NLO performance.

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Section: Borate Crystals Containing the B-o Combinational Groupsmentioning

confidence: 97%

Section: The Borates Containing B-o Groups and Other Nlo Active Groupsmentioning

confidence: 99%

Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

et al. 2017

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“…Many borate halides have been reported in our and other groups [24][25][26]. For example, the borate halides K 3 B 6 O 10 Cl (KBOC) [27][28][29][30][31][32], Ba 4 B 11 O 20 F [33], M 3 B 6 O 11 F 2 (M=Ba, Sr, Pb) [34][35][36], Li 3 Ca 9 (BO 3 ) 7 · 2[LiF] [37], etc.…”

Section: Introductionmentioning

confidence: 99%

Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

Yang

et al. 2015

Journal of Materiomics

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The crystal of K 3 B 6 O 10 Cl with sizes up to 35 mm × 35 mm × 11 mm was successfully grown by TSSG method. The preliminary measurements for linear, NLO optical and other functional properties have also been studied on the grown crystals. K 3 B 6 O 10 Cl is a potential UV NLO material for direct FHG of the 1112 nm laser.Abstract: Single crystal of K 3 B 6 O 10 Cl with size of 35 mm × 35 mm × 11 mm was grown by the TSSG method for the first time. In the crystal growth process, the cooling rate, the rotating speed and seed direction have been investigated. Based on the measurement of refractive-index from UV to NIR region, the limit of type-I phase matching second harmonic generation wavelength was calculated to be 272 nm, which is a little shorter than that of LiB 3 O 5 (277 nm). Thermal properties including specific heat, thermal diffusion and thermal conductivity were performed on the crystal. In addition, polarization measurements demonstrate that although K 3 B 6 O 10 Cl is polar, the material is not ferroelectric.

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“…1 5 Furthermore, the basic structural units in this system have no absorptions in the UV range, which are conducive to obtain crystals with large band gap and UV transparency. Therefore, continuous efforts are going on for developing UV NLO crystals in this system, and new crystals with good NLO properties include Ca 5 (BO 3 3 F, 6 BaMgBO 3 F, 7 BaCaBO 3 F, 8 Sr 3 B 6 O 11 F 2 , 9 Ba 4 B 11 O 20 F 1a and Ba 3 B 6 O 11 F 2 , 1b etc.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Characterization and Nonlinear Optical Property of the Barium Borate Halide Ba2B5O9Cl · 0.5H2O

Zhang¹,

Zhang²,

Jia³

et al. 2015

mater focus

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The hydrate barium borate halide Ba 2 B 5 O 9 Cl · 0.5H 2 O was synthesized under mild hydrothermal system BaCl 2 -H 3 BO 3 -H 2 O and its structure is determined by single-crystal X-ray diffraction method. The second harmonic generation (SHG) measurement indicates that Ba 2 B 5 O 9 Cl · 0.5H 2 O exhibits a type I, non-phase-matching response of approximately 1 × KH 2 PO 4 (KDP). The effect of the structural units on the polarizability of the structure was discussed by dipole moment calculations based on the bond valence method. IR spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and thermal properties of Ba 2 B 5 O 9 Cl · 0.5H 2 O were studied.

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Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response

Cited by 27 publications

References 31 publications

Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

Synthesis, Characterization and Nonlinear Optical Property of the Barium Borate Halide Ba<SUB>2</SUB>B<SUB>5</SUB>O<SUB>9</SUB>Cl · 0.5H<SUB>2</SUB>O

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