2019
DOI: 10.1039/c9ta07689a
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Sr2Fe1.4Mn0.1Mo0.5O6−δ perovskite cathode for highly efficient CO2 electrolysis

Abstract: An all-ceramic cermet cathode based on perovskite-oxide Sr2Fe1.4Mn0.1Mo0.5O6−δ and samaria-doped ceria shows unprecedented performance in solid oxide electrolysis of pure CO2.

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Cited by 76 publications
(46 citation statements)
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“…The test of 12.8 wt.% GDC‐SFM cell showed stability for over 60 h at 1.2 V and 800 °C. By doping of SFM with Mn, Sr 2 Fe 1.4 Mn 0.1 Mo 0.5 O 6– δ (SFMM) showed similar redox stability as SFM but enhanced in oxygen transport, CO 2 adsorption and reduction kinetics 63. The SFMM‐SDC composite electrode further exhibits excellent coking resistance, which can achieve a current density of 1.35 A cm 2 at 800 °C at 1.5 V for electrolysis of pure CO 2 .…”
Section: Development Of Soec Cathodes For Co2electrolysismentioning
confidence: 99%
“…The test of 12.8 wt.% GDC‐SFM cell showed stability for over 60 h at 1.2 V and 800 °C. By doping of SFM with Mn, Sr 2 Fe 1.4 Mn 0.1 Mo 0.5 O 6– δ (SFMM) showed similar redox stability as SFM but enhanced in oxygen transport, CO 2 adsorption and reduction kinetics 63. The SFMM‐SDC composite electrode further exhibits excellent coking resistance, which can achieve a current density of 1.35 A cm 2 at 800 °C at 1.5 V for electrolysis of pure CO 2 .…”
Section: Development Of Soec Cathodes For Co2electrolysismentioning
confidence: 99%
“…In general, the catalysis performance of perovskite‐based oxides can be improved by partially doping the A‐site/B‐site with alkaline earth metal ions or valence‐active ions. The substitution may apply or influence the B‐O‐B' redox couples to facilitate electron and ion transportation and increase the surface oxygen vacancy concentration for the enhanced adsorption and diffusion of CO 2 , thereby effectively improve the catalysis activity 15–17. Zhang et al.…”
Section: Introductionmentioning
confidence: 99%
“…Jiang et al. synthesized Sr 2 Fe 1.4 Mn 0.1 Mo 0.5 O 6– δ ‐Ce 0.8 Sm 0.2 O 1.9 (SFMM 0.1 ‐SDC) as the fuel electrode, the CO 2 reduction kinetics was accelerated compared with SFM, and the current density reached 1.35 A cm −2 at 1.5 V and 800 °C 17.…”
Section: Introductionmentioning
confidence: 99%
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