“…High melting point, high strength, and high chemical stability, as well as other special peculiarities, such as a low electronic work function, stable specific resistance, a low expansion coefficient in some temperature ranges, and high neutron absorbability, make these materials suitable for use as component of high-energy optical systems [7][8][9], sensors for high-resolution detectors [10], electrical coatings for resistors, thermionic materials [11,12], and nuclear technology [13]. SmB 6 , one of the rare-earth hexaborides, is a classical fluctuating-valence semiconductor [14] and Kondo insulators [15], and have the relatively lower work function (3.11 eV) [16], which can make it to be used as potential thermionic emission materials. Therefore, samarium hexaboride has attracted considerable contemporary interest from both the fundamental and practical viewpoints.…”