“…Ligand strategies have emerged as a prominent approach to alleviating the dense arrangement of PbI 2 in the first step. By forming ligands with PbI 2 and subsequently replacing them with organic salts, these strategies influence reaction pathways and rates, driving favorable perovskite formation. − While in the cases of hybrid two-step method prepared on textured silicon as substrates, the first step is more challenging to control the inorganic components or form ligands compared with the solution method. Yi et.al introduced a Cl-containing alloy-mediated approach in a sequential vacuum evaporation method, enhancing perovskite film quality by promoting organic ammonium halide diffusion and perovskite conversion reaction .…”