Spraying and Mixing Characteristics of Urea in a Static Mixer Applied Marine SCR System

Abstract

The most effective de-NOx technology in marine diesel applications is the urea-based selective catalytic reduction (SCR) system. The urea-SCR system works by injecting a urea solution into exhaust gas and converting this to NH3 and CO2. The injection, mixing, and NH3 conversion reaction behavior of the urea-water solution all have a decisive effect on the performance of the system. To improve de-NOx efficiency, it is important to provide enough time and distance for NH3 conversion and uniform distribution prior to the solution entering the catalyst. In this study, therefore, the characteristics of gas flow, NH3 conversion, and its distribution are investigated with a static mixer by means of numerical methods, providing a special advantage to ship manufacturing companies through the optimization of the urea-SCR system. The results show that the inclusion of the mixer induces strong turbulence and promotes the NH3 conversion reaction across a wider region compared to the case without the mixer. The mean temperature is 10 °C lower due to the activated endothermic urea-NH3 conversion reaction and the NH3 concentration is 80 PPM higher at 1D than those without the mixer. Moreover, the uniformity of NH3 distribution improved by 25% with the mixer, meaning that the de-NOx reaction can take place across all aspects of the catalyst thus maximizing performance. In other words, ship manufacturing companies have degrees of freedom in designing post-processing solutions for emissions by minimizing the use of the reduction agent or the size of the SCR system.

Numerical evaluation of urea-mixing devices for close-coupled selective catalytic reduction systems

“…Hui et al [18] pointed out that it is difficult to achieve the uniform distribution of NH 3 using hole-type UWS injectors. While, Jang et al [19] observed a decrease in exhaust gas temperature in a marine SCR system equipped with a mixer, along with a rise in the ammonia concentration. This was attributed to the endothermic thermolysis reaction and the increased area where the reaction took place.…”

Development and verification of model predictive control strategy for selective catalytic reduction with rapid prototyping

“…7 The amount of urea required by the marine SCR system is larger, which is more likely to cause excessive ammonia escape. 8 Model predictive control (MPC) is a sampling control algorithm based on object model. It can deal with complex control problems with constrained control action and solve the hysteresis problem.…”

“…7 The amount of urea required by the marine SCR system is larger, which is more likely to cause excessive ammonia escape. 8…”