Spinodal Decomposition of Filled Polymer Blends: The Role of the Osmotic Effect of Fillers
A. I. Chervanyov
Abstract:The reported work addresses the effect of fillers on the thermodynamic stability and miscibility of compressible polymer blends. We calculate the spinodal transition temperature of a filled polymer blend as a function of the interaction energies between the blend species, as well as the blend composition, filler size, and filler volume fraction. The calculation method relies on the developed thermodynamic theory of filled compressible polymer blends. This theory makes it possible to obtain the excess pressure … Show more
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