Spin-order and magnetic properties of BaZn2Fe16O27 (Zn2-W) hexagonal ferrite

Synthesis and Magnetic Properties of (Zn²⁺Ti⁴⁺) Substituted W-type and Y-type Ferrites

“…In order to discuss the relationship between the change in σS and the cation distribution in the W-type structure, we consider the spin configuration of the W-type structure. Table 1 shows the distribution of the transition metal sites and the expected directions of the magnetic moments in the R and S blocks of the W-type structure 38) . Fig.…”

W-type hexaferrite nanoparticles: A consideration for microwave attenuation at wide frequency band of 0.5–10GHz

“…These blocks arrange themselves together in such a manner along the c-axis to form repeated structure of RSSR*S*S* [4]. The various octahedral and tetrahedral sites in these blocks contain seven different types of sublattices, occupied by various cations [21]. Positions of these ions strongly affect the electrical as well as magnetic properties of W-type hexaferrites.…”

Tailoring of structural, electrical and magnetic properties of BaCo2 W-type hexaferrites by doping with Zr–Mn binary mixtures for useful applications

“…4, confirming the pattern of pure W-type hexaferrite [8,22]. The spectra were analyzed in terms of superposition of six Zeeman sextets.…”

“…The spectra were analyzed in terms of superposition of six Zeeman sextets. The assignments of sub-lattices for different peaks were made based on the scheme adopted for W-type hexagonal ferrites [8,10] demonstrating different positions of iron magnetic sub-lattices in the structure. Mössbauer spectrum of the undoped sample shows that the k 1 sub-lattice is noticeably distinguishable and is distinct.…”

“…12k, 4f VI , 6g, 4f (octahedral coordination), 4e, 4f IV (tetrahedral coordination) and 2d (bipyramidal coordination) [8,9]. However, there are only five magnetically non-equivalent sub-lattices from magnetic perspective, i.e.…”