“…On the other hand, other NMR ͑Ref. 13͒ and neutron scattering 18 experiments find a constant spin gap upon Ca substitution for the ladders as well. Chemical pressure by Ca substitution for Sr as well as physical pressure reduces the interlayer distances 19 and increases the twisting of the CuO 2 chain.…”
“…On the other hand, other NMR ͑Ref. 13͒ and neutron scattering 18 experiments find a constant spin gap upon Ca substitution for the ladders as well. Chemical pressure by Ca substitution for Sr as well as physical pressure reduces the interlayer distances 19 and increases the twisting of the CuO 2 chain.…”
“…For the low temperature magnetic response, the ladders do not contribute significantly since they exhibit a non-magnetic ground state and a large spin gap of ∆ ≈ 380 K for the whole doping series Sr 14−x Ca x Cu 24 O 41 . [8][9][10] Thus, the low temperature magnetic response of these compounds is determined by the weakly coupled CuO 2 spin chains. The chains consist of edge-sharing CuO 4 -plaquettes containing Cu 2+ -ions with S = 1 2 in the undoped case.…”
We report on magnetisation measurements of Sr14−xCaxCu24O41, with 0 ≤ x ≤ 12, in magnetic fields up to 16 T. The low temperature magnetic response of the CuO2 spin chains changes strongly upon doping. For x = 0, the ground state with nearly independent dimers is confirmed. Reduction of the number of holes in the chains through Ca-doping leads to an additional contribution to the magnetisation, which depends linearly on the magnetic field. Remarkably, the slope of this linear contribution increases with the Ca content. We argue that antiferromagnetic spin chains do not account for this behaviour but that the hole dynamics might be involved.
“…Up to now, the ground state of this spin-ladder superconductor in ambient pressure has not been well understood because of contradictive reports from different experimental methods. 9,10 Similar to the high temperature superconducting cuprates with 2D lattices, investigating the physics of the normal phase of Sr 14−x Ca x Cu 24 O 41 should provide a solid basis to understand the superconducting mechanism. Therefore, it is extremely important to reveal the physics of the normal state of this spin-ladder compound in order to find out the differences between Sr 14−x Ca x Cu 24 O 41 and other 2D superconductors, and further our understanding to their superconducting mechanisms.…”
The spin-gap evolution upon Ca doping in Sr 14−x Ca x Cu 24 O 41 was systematically investigated using inelastic neutron scattering. We discover that the singlet-triplet spin-gap excitation survives in this series with x up to 13, indicating the singlet dimer ground state in these compounds. This observation corrects the previous speculation that the spin gap collapses at x ∼ 13 by the NMR technique. The strong intensity modulation along Q H in x = 0 gradually evolves into a Q-independent feature in x > 11. This could be attributed to the localized Cu moment magnetism developing into an itinerant magnetism with increasing x. It is a surprise that the spin gap persists in the normal state of this spin-ladder system with metallic behavior, which evidences the possibility of magnetically mediated carrier pairing mechanism in a two-leg spin-ladder lattice.
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