We consider a spin-1/2 Ising-XYZ distorted diamond chain with the XYZ interaction between the interstitial Heisenberg dimers, the nearest-neighbor Ising coupling between the nodal and interstitial spins, respectively, and the second-neighbor Ising coupling between the nodal spins. The ground-state phase diagram of the spin-1/2 Ising-XYZ distorted diamond chain exhibits several intriguing phases due to the XY anisotropy and the second-neighbor interaction, whereas the model can be exactly solved using the transfer-matrix technique. The quantum entanglement within the Heisenberg spin dimers is studied through a bipartite measure concurrence, which is calculated from a relevant reduced density operator. The concurrence may either show a standard thermal dependence with a monotonous decline with increasing temperature or a more peculiar thermal dependence accompanied with reentrant behavior of the concurrence. It is conjectured that the bipartite entanglement between the interstitial Heisenberg spin pairs in the natural mineral azurite is quite insensitive to the applied magnetic field and it persists up to approximately 30 Kelvins.