Ferromagnetic semiconductors with
structural flexibility are an
indispensable feature for future flexible spin-electronic applications.
In this case, we introduce magnetic ingredients into an organic semiconductor,
namely, pentacene, to form a ferromagnetic organic semiconductor (FOS).
The first observation for ferromagnetic Ni-doped pentacene semiconductors
at room temperature in the field of semiconductor spintronics is reported
in this article. To date, the mechanism of FOSs with ferromagnetism
is not understood yet, especially when their Curie temperature is
enhanced above room temperature. Here, we demonstrate dopants of Ni
atoms and the modulation of the growth temperature in the FOS films
to achieve room-temperature ferromagnetic properties in a series of
FOS films, one of which has a maximum coercivity of 257.6 Oe. The
spin-exchange interaction between a Ni atom and a pentacene molecule
is detected through the magnetic hysteresis obtained using a superconducting
quantum interference device magnetometer. We verify the effectiveness
of this spin coupling through magnetic force microscopy, Raman spectroscopy,
scanning Kelvin probe microscopy, and theoretical simulation. A model
for the indirect spin coupling between Ni atoms is proposed for the
mechanism of room-temperature ferromagnetic ordering of spins due
to the exchange force indirectly. We believe that the π-electrons
of pentacene molecules at the triple state for this model can support
the spin coupling of electrons of Ni atoms. Our findings facilitate
the development of brand-new spintronic devices with structural flexibility
and room-temperature ferromagnetism.