The emerging field of spintronics explores the many possibilities offered by the prospect of using the spin of the electrons for fast, nanosized electronic devices. The effect of magnetization acting on a current is the essence of giant or tunnel magnetoresistance. Although such spintronics effects already find technological applications, much of the underlying physics remains to be explored. The aim of this article is to demonstrate the importance of spin mixing in metallic nanostructures. Here we show that magnetic clusters embedded in a metallic matrix exhibit a giant magnetic response of more than 500% at low temperature, using a recently developed thermoelectric measurement. This method eliminates the dominating resistivity component of the magnetic response and thus reveals an intrinsic spin-dependent process: the conduction-electron spin precession about the exchange field as the electron crosses the clusters, giving rise to a spin-mixing mechanism with strong field dependence. This effect appears sensibly only in the smallest clusters, that is, at the level of less than 100 atoms per cluster.
Spintronics seeks to exploit the interplay of spin-polarized conduction electrons and magnetization in nanostructures. Spin-dependent scattering leads to giant magnetoresistance [1][2][3][4][5] (GMR) and tunnelling magnetoresistance [6][7][8] , whereas the converse effect of a spin-polarized current on the magnetization 9-11 can be taken advantage of in magnetoresistive memory bits 12 and gigahertz oscillators 13 . GMR as a field sensing measurement of a resistivity ratio R/R is dominated by non-magnetic and spin-independent scattering processes determining R. Instead, the thermoelectric measurement protocol developed in our laboratory 14 depends on the first derivative of R with respect to the temperature and thus suppresses this resistive contribution. This allows us to fully reveal the otherwise negligible spin-mixing processes. In multilayers this mechanism is essentially a spin-dependent Peltier effect that roughly doubles the field sensitivity compared with GMR 14 . Here we have applied this measurement protocol to granular clusterassembled materials 15 , the geometry of which is not appropriate for a Peltier effect. Hence a clearly different microscopic mechanism takes a predominant role here. We invoke the predominance of spin mixing caused by a spin-precession effect 16 that is completely different in nature. Spin mixing was predicted to decrease GMR responses, as it scrambles the two spin channels of conduction. In our measurement scheme, on the contrary, it results in a 100-fold increase of the field response compared with GMR. The combined use of cluster-assembled materials and a novel measurement method thus reveal a different spin transport effect and may open a new route towards possible applications.Samples were prepared (see the 'Methods' section) according to the strategy of 'cluster-assembled materials' (Fig. 1). Briefly, the samples consist of thin films of copper in which well-defined cobalt clu...