Spin Crossover Quenching by “Racemization” in a Family of trans-1,2-Di(tetrazol-1-yl)cyclopentane-Based Fe(II) 1D Coordination Polymers
Vladyslav Maliuzhenko,
Marek Weselski,
Janusz Gregoliński
et al.
Abstract:Optically pure (RR)-and racemic (RR/SS)-trans-1,2di(tetrazol-1-yl)cyclopentane were synthesized and used to prepare homo-and heterochiral Fe(II) coordination compounds. [Fe((RR/SS)-form a family of one-dimensional coordination polymers. Fe(II) cations in these complexes are characterized by a heteroleptic coordination environment: the neighboring metal centers are bridged by two 1,2-di(tetrazol-1-yl)cyclopentane molecules, while the nitrile molecules (acetonitrile or propionitrile, respectively) occupy the axi… Show more
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