Abstract:The development of strategies to efficiently capture and release gas is one of the most urgent topics in modern applied chemistry. In this respect, the modulation of the affinity for the gas molecule upon application of an external stimulus appears as fascinating strategy to reduce the energy penalty of the release process. In this work we provide the proof- of-concept for a novel temperature-induced gas release strategy in porous materials with desorption occurring upon a spin crossover transition of metal ce… Show more
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