Spin-Cluster Glassy and Long-Range Ordered Magnetic States in Honeycomb-Layered Compositionally Complex Oxides Na3–xLixT2SbO6 (T = Cu1/3Ni1/3Co1/3)
Vladimir B. Nalbandyan,
Tatyana M. Vasilchikova,
Maria A. Evstigneeva
et al.
Abstract:The concept of high-entropy oxides has triggered extensive research of this novel class of materials because their numerous functional properties are usually not mere linear combinations of those of the components. Here, we introduce the new series of compositionally complex honeycomb-layered magnets Na 3−x Li x T 2 SbO 6 (T = Cu 1/3 Ni 1/3 Co 1/3 ). An unusual feature of the system is its nonmonotonous dependences of the monoclinic lattice parameters b and β on x. Rietveld refinement of the crystal structures… Show more
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