The speed of sound in 3,3,3-trifluoropropene
(R-1243zf) in the
gaseous phase has been measured using a fixed-path cylindrical resonator.
The experiment was conducted along nine quasi-isochoric lines in the
temperature range of (313 to 363) K and pressure range of (170 to
983) kPa. The speed of sound at 92 state points (p,T) was obtained from accurate measurements of resonant frequencies
of seven acoustic modes. The overall relative expanded uncertainty
at the confidence level of 0.95 in the speed of sound measurements
is estimated to be 1.8 × 10–4. The ideal-gas
heat capacity at constant pressure for R-1243zf was determined over
the temperature range from the speed of sound measurement with a relative
expanded uncertainty (k = 2) of less than 0.5%, and
the second acoustic virial coefficient was also derived. The temperature
dependence of the ideal-gas heat capacity at constant pressure was
correlated with a polynomial approximation relationship. The measured
speed of sound and the derived ideal-gas heat capacities and second
acoustic virial coefficient were also compared with calculations of
the available equation of state of 3,3,3-trifluoropropene.