2013
DOI: 10.1021/je400122k
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Speed of Sound, Density, and Derivative Properties of Ethyl Myristate, Methyl Myristate, and Methyl Palmitate under High Pressure

Abstract: Speeds of sound have been measured in ethyl myristate (C 16 H 32 O 2 ), methyl myristate (C 15 H 30 O 2 ), and methyl palmitate (C 17 H 34 O 2 ) at pressures up to 100 MPa along isotherms ranging from (293.15 to 403.15) K. The measurements were carried out using a pulse echo technique operating at 3 MHz. Additional compressed liquid density measurements were performed from (293.15 to 393.15) K with pressures from (0.1 to 100) MPa in order to evaluate isentropic compressibility using speed of sound measurements… Show more

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Cited by 65 publications
(24 citation statements)
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“…All the details concerning the various stages in the calculation of these properties are discussed in a previous paper [16]. In order to adjust parameters, it is necessary to evaluate the parameter of v ref from atmospheric density data and then to estimate the coefficients a, b and d by minimizing the following objective function:…”
Section: Resultsmentioning
confidence: 99%
“…All the details concerning the various stages in the calculation of these properties are discussed in a previous paper [16]. In order to adjust parameters, it is necessary to evaluate the parameter of v ref from atmospheric density data and then to estimate the coefficients a, b and d by minimizing the following objective function:…”
Section: Resultsmentioning
confidence: 99%
“…We have recalculated the constant A in Eq. (10) by fitting densities of methyl palmitate [57], methyl oleate [1,58], and methyl linoleate [27,58], since they were the most abundant FAMEs in the biodiesels. The fitting of Eq.…”
Section: Density Prediction 431 the Group Contribution Methods (Gcmentioning
confidence: 99%
“…where the subscript i refers to a subset with an average deviation value (AAD%) i for the (T, k m ) data and N s is the number of systems (subsets) involved. The OAAD% for equations (14) and (16) are 0.17 and 0.19%, respectively. Table 6 Molar compressibility (k m ) for FAME, synthetic and produced biodiesels.…”
Section: Molar Compressibilitymentioning
confidence: 99%