Spectroscopic properties of neodymium doped magnesium zinc sulfophosphate glass: Synergistic effects of titanium and silver nanoparticles embedment

Yusof, N.N.; Ghoshal, Sib Krishna; Jupri, Siti Aishah

doi:10.1016/j.optmat.2020.110266

Cited by 4 publications

(5 citation statements)

References 81 publications

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“…This finding is in agreement with previous studies which show amplification of SPR band intensity that aligned with NPs size. There is no shift of SPR bands due to unchanged shape or dimensions [7][8].…”

Section: Surface Plasmon Resonance Absorption Bandsmentioning

confidence: 99%

“…The results elucidates that HT enhances PL through SPR intensification. The glass that was heat-treated for 6 hours shows declining in PL intensity due to high electron scattering or pure dephasing of the plasmon resonance [7]. The damping cause non-radiative channel and impact the phonon-photon density of the Nd 3+ ion.…”

Section: Nir Photoluminescencementioning

confidence: 99%

“…Nevertheless, their small emission cross−section of Nd 3+ has limit them into practical application. Thus, inserting metal nanoparticles (NPs) into these glass has been proposed in order to enhance the luminescence intensity of Nd 3+ ions [7][8]. The emission gain of Nd 3+ likely to be improve by local surface plasmon resonance (SPR) effect through (i) enlargement of local electric field (LFE) and (ii) energy transfer (ET) [9].…”

Section: Introductionmentioning

confidence: 99%

“…Plasmon resonance bands of Ti NPs has shown able to improve luminescence chloroplasts in Bio-LEDs [10]. Thus in the current work, titanium nanoparticles (Ti NPs) were attempted to be grown within the glass and then heat-treated to oversee their effect on luminescence properties of REI doped glass [7]. As for now, no in-depth study has been conducted to oversee the impact of heat treatment (HT) on the optical properties of Nd 3+ doped magnesium zinc sulfophosphate glass when embedded in both pure titanium micro/nanoparticles (Ti NPs).…”

Section: Introductionmentioning

confidence: 99%

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Titanium Nanoparticles Modified NIR Emission of Neodymium Doped Magnesium Zinc-Sulfophosphate Glass: Effect of Heat Treatment on Surface Plasmon Resonance Bands

Yusof

Hashim

Aziz

et al. 2022

J. Phys.: Conf. Ser.

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New type plasmonic sensitizer, titanium nanoparticles (Ti NPs) shown potential in enhancing photoluminescence of rare-earth ions (REIs) as doped into magnesium zinc-sulfophosphate (MZS) glass for optical to optic application. Here, neodymium ions (Nd3+)-doped MZS glass with Ti NPs inclusion gone heat treatment (HT) at 450°C for 6 and 12 hours in order to tune the NPs size and tailor their plasmonic strength. The sample was characterized using X-ray diffractometer (XRD), high-resolution transmission electron microscope (HRTEM), and photoluminescence (PL) spectrometer. Heat treatment (HT) grows Ti NPs with a mean size ≈ 16 nm. The SPR bands are probed around 585and 739 nm. The SPR band intensities change with HT duration. The NIR PL bands were perceived around 878 nm, 1050 nm and 1322 nm corresponding to 4F3/2→4I9/2, 4F3/2→4I11/2 and 4F3/2→4I13/2 transitions, accordingly. The PL transition 4F3/2→4I9/2 (878 nm) and 4F3/2→4I13/2 (1322 nm) is enhanced about 1.44 and 1.52 times respectively, after 12 hours HT. The results show that HT enhances PL through SPR amplification. These findings may be useful in developing solid-state lasers and optical materials.

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Section: Surface Plasmon Resonance Absorption Bandsmentioning

confidence: 99%

Section: Nir Photoluminescencementioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Titanium Nanoparticles Modified NIR Emission of Neodymium Doped Magnesium Zinc-Sulfophosphate Glass: Effect of Heat Treatment on Surface Plasmon Resonance Bands

Yusof

Hashim

Aziz

et al. 2022

J. Phys.: Conf. Ser.

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“…Plasmonic nanoparticles (NPs) such as gold [1], silver [2], titanium [3] and titanium nitride [ [4], [5], [6]] exhibit unique optical properties by enhancing the local field proximity rare earth ions (REI) doped glass whenever their natural frequency matched with excitation frequency. This phenomenon is known as local surface plasmon resonance (LSPR).…”

Section: Introductionmentioning

confidence: 99%

Exploring the Impact of Plasmonic Nanoparticles on Photoluminescence of Er³⁺ - Doped Sodium Zinc Tellurite Glass for Solid-State Laser Applications

Nur Nabihah Yusof,

Muhammad Noorazlan Abd Azis,

Nurulhuda Mohammad Yusoff

2023

KIMS/CUMR/MShKP

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The present work compares the impact of embedding silver (Ag), gold (Au), titanium (Ti), and titanium nitride (TiN) nanoparticles (NPs) on the absorption, photoluminescence, and Judd Ofelt properties of erbium-doped sodium zinc tellurite glass (TNZE), known as reliable solid-state laser media. Ten absorption bands of Er3+ ions in the range of 400-1600 nm are attainable where their bands correspond to their own 4f transitions. Three prominent photoluminescence (PL) bands of Er3+ ions were observed at approximately 525 nm, 545 nm, and 630 nm, corresponding to the transitions 2H11/2®4I15/2, 4S3/2®4I15/2 and 4F9/2®4I15/2, respectively. TZNE with 0.15 mol% of TiN NP inclusion showed the highest PL enhancement factor about 35 times, followed by Ti (17 times), Ag (10 times), and Au NPs (5 times), accordingly. This enhanced PL can be attributed to the strong local field induced by the localized surface plasmon resonance (LSPR) of the plasmonic NPs lies within 490-630 nm, which assists the transitions of Er3+ ions. The Judd Ofelt parameter was calculated and the TNZE glass with 0.15 mol% of TiN NPs inclusion disclosed the highest spectroscopic quality with a value of 3.57, compared to the TNZE glass with Ti (1.19), Au (0.59), and Ag NPs (0.90) inclusions. This research revealed several potential glass compositions with plasmonic nanoparticles that are attractive for the development of solid-state laser materials.

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Spectrographic analysis of zinc-sulfate-magnesium-phosphate glass containing neodymium ions: Impact of silver–gold nanoparticles plasmonic coupling

Yusof

Hashim

Ghoshal

et al. 2022

Journal of Luminescence

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Spectroscopic properties of neodymium doped magnesium zinc sulfophosphate glass: Synergistic effects of titanium and silver nanoparticles embedment

Cited by 4 publications

References 81 publications

Titanium Nanoparticles Modified NIR Emission of Neodymium Doped Magnesium Zinc-Sulfophosphate Glass: Effect of Heat Treatment on Surface Plasmon Resonance Bands

Titanium Nanoparticles Modified NIR Emission of Neodymium Doped Magnesium Zinc-Sulfophosphate Glass: Effect of Heat Treatment on Surface Plasmon Resonance Bands

Exploring the Impact of Plasmonic Nanoparticles on Photoluminescence of Er³⁺ - Doped Sodium Zinc Tellurite Glass for Solid-State Laser Applications

Spectrographic analysis of zinc-sulfate-magnesium-phosphate glass containing neodymium ions: Impact of silver–gold nanoparticles plasmonic coupling

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