2007
DOI: 10.1016/j.saa.2006.12.034
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Spectroscopic investigations of new binuclear transition metal complexes of Schiff bases derived from 4,6-diacetylresorcinol and 3-amino-1-propanol or 1,3-diamino-propane

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Cited by 70 publications
(25 citation statements)
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“…The shift of the stretching frequencies of azomethine m(-C@N-) group of the metal complexes to lower frequencies which lie in the range of 1620-1576 cm À1 , compared with the free ligand band at 1629 cm À1 , may be due to coordination of two azomethine groups to metal ions [22,48].…”
Section: Infrared Spectramentioning
confidence: 94%
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“…The shift of the stretching frequencies of azomethine m(-C@N-) group of the metal complexes to lower frequencies which lie in the range of 1620-1576 cm À1 , compared with the free ligand band at 1629 cm À1 , may be due to coordination of two azomethine groups to metal ions [22,48].…”
Section: Infrared Spectramentioning
confidence: 94%
“…The assignments were aided by comparison with the vibrational frequencies of the free ligand and its related compounds [22,48,49]. Fig.…”
Section: Infrared Spectramentioning
confidence: 99%
“…Further supporting is presence of bands at 3043 and 2948 cm -1 , attributed to the absorption band of DAP symmetric and asymmetric C-H, respectively. Other bands include 1561 cm -1 (NH 2 stretching), 1457 cm -1 (CH 3 and CH 2 asymmetrical stretching), and 1325 cm -1 (CH 3 and CH 2 symmetrical stretching) [15]. As for pristine and nanocomposite foam spectra, presence of peaks at 1712 cm -1 , 1509 cm -1 , and 1216 cm -1 confirms the formation of PU network as these bands represent the bending vibration C=O, N-H, and C-N, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…In spite of the spectrophotometric method is rapid, cheap and simple, the direct spectrometric measurements show lack of specificity because the spectra are strongly overlapped. In such cases the chemometric techniques become an indispensable tool to overcome these problems [15][16][17][18][19] .…”
Section: Methodsmentioning
confidence: 99%