“…In some cases, the rotational temperature of the intermediate species of hot gases is very close to the kinetic temperature, because the translational and rotational energies of a molecule equilibrate within a trajectory of a few mean free path length by collisional processes with other species (Lapworth, 1974). In nonequilibrium systems, as in hypersonic flows (Fujita et al, 2002;Ivanov et al, 2008;Tsuboi;Matsumoto, 2006), supersonic combustion (Do et al, 2008), or plasmas generated by spacecraft during reentry (Blackwell et al, 1997), the various forms of energy are not in equilibrium, and there is not one temperature value able to describe all physical chemistry processes in course (Reif et al, 1973). In these cases, rotational temperature is useful to provide information about chemical reactivity of the medium and produced thermal energy (Acquaviva, 2004).…”