2008
DOI: 10.1080/09638280701623810
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Spectroscopic investigation of the seeds of chilli (Capsicum annumL.)

Abstract: In addition to their use as food and spice, chillies have been popular in both Ayurvedic and homoeopathic treatments since ancient times. Elemental analyses on their seeds with the help of X-ray fluorescence spectra reveal the presence of hitherto undetected magnesium, along with sulphur and chlorine. Fourier transform infrared and Fourier transform Raman spectra of the seeds reveal the presence of specific functional groups, attributed to the different bands present in the spectra. Ascorbic acid, reported to … Show more

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Cited by 12 publications
(4 citation statements)
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References 14 publications
(15 reference statements)
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“…Because the spectral response is linear with analyte concentration, it is possible to develop a calibration (mathematical model) to predict the concentration of an analyte; however, this mathematical model must first be developed using a primary/reference analytical method for the range of concentrations that are of interest for a particular sample. The mathematical model used is usually some form of a linear regression (PCR or PLS); however, neural network algorithms also have been used. There are only a few examples of using a Raman based approach for seeds/grain analysis and no reports to apply the methodology to whole intact soybeans. Despite the potential for higher chemical specificity and the availability of data analysis methods, the use of Raman spectroscopy for seed/grain analysis has not been widespread, largely due to a relatively weak Raman signal.…”
Section: Introductionmentioning
confidence: 99%
“…Because the spectral response is linear with analyte concentration, it is possible to develop a calibration (mathematical model) to predict the concentration of an analyte; however, this mathematical model must first be developed using a primary/reference analytical method for the range of concentrations that are of interest for a particular sample. The mathematical model used is usually some form of a linear regression (PCR or PLS); however, neural network algorithms also have been used. There are only a few examples of using a Raman based approach for seeds/grain analysis and no reports to apply the methodology to whole intact soybeans. Despite the potential for higher chemical specificity and the availability of data analysis methods, the use of Raman spectroscopy for seed/grain analysis has not been widespread, largely due to a relatively weak Raman signal.…”
Section: Introductionmentioning
confidence: 99%
“…To the weak band at 3509.51 cm -1 in the FTIR spectrum, one could assign the O-H stretching vibration. As no doublet at a separation of approximately 70 cm -1 is evident, the N-H stretching vibration is ruled out (Colthup et al, 1964;Gohain Barua et al, 2008). A strong and broad band in the region 3700-3100 cm -1 is usually due to O-H stretching vibrations in water (Colthup et al, 1964).…”
Section: Resultsmentioning
confidence: 99%
“…Ustunda 242 also exploited the sensitivity of polarised EDXRF to assess elemental concentrations in peppermint (Mentha piperita), thyme (Thymus vulgaris) and sumac (Rhus glabra), all plants commonly used in the preparation of Turkish foods. Barua et al 243 used XRF for elemental analysis of the seeds of chilli (Capsicum annum L.), popular as a spice and also used in homoeopathic treatments. Fourier transform Raman and FTIR spectra showed the presence of specific functional groups but ascorbic acid, a vitamin found in chilli peppers was conspicuous by its absence in the seeds.…”
Section: Geological and Industrial Mineralsmentioning
confidence: 99%