Equilibria
occurring between 2-hydroxybenzoic acid (salicylic acid,
H2L) and calcium(II), magnesium(II), and nickel(II) have
been studied by potentiometric titrations with glass electrodes at
298.15 K in self-medium constituted of 1.05 mol·kg–1 NaHL. The self-medium composition can be considered constant since
only a small amount of ligand HL– is transformed
in the reaction products. The hydrogen ion concentration was varied
from 10–2 mol·kg–1 to incipient
precipitation of a basic salt of each metal, whose formation depends
on the particular metal. The total metal concentration, C
M, ranged from 3.05·10–3 mol·kg–1 to 10.01·10–3 mol·kg–1. The higher C
M value
was imposed in order to avoid changes in the ionic medium and in the
activity coefficients. The experimental data have been explained by
assuming the formation of the complexes: CaL; MgL, MgL2
2–, and MgL3
4–; NiL
and NiL2
2–.