CaF 2 crystals doped with Yb 3+ ions have been studied by electron paramagnetic resonance (EPR) and optical spectroscopy. EPR spectra of paramagnetic centers (PCs) for eubic (Te) and tetragonal (T,ot) symmetries were identified. Empirical energy level diagrams were established and crystal field parameters were determined. Information on the CaF2:Yb 3 § phonon spectra was obtained from the electron-vibrational structure of the optical spectra. The crystal field parameters were used to analyze the crystal lattice distortions in the vicinity of the Yb 3 § ion. Within the framework of a superposition model, ir is established that four F-ions located symmetrically with respect to the fourfold axis from the side of the ion-compensator approach the impu¡ ion and deviate from the PC axis. The second set of four fluofine ions also approaches the Yb 3+ ion and the PC axis. The ion-compensator F-also approaches considerably the impu¡ ion.