Spectral Behavior and Photophysical Parameters of Dihydrophenanthro[9,10-e][1,2,4]Triazine Derivative Dyes in Sol–gel and Methyl Methacrylate Polymer Matrices

Abstract

This paper deals the optical and photophysical properties of dihydrophenanthro [9,10-e] [1,2,4] triazine fluorescent derivative dyes doped in Silicate based sol–gel, homo-poly methyl methacrylate (PMMA). Solid hosts effect on the optical and photophysical parameters such as molar absorptivity, cross sections of singlet–singlet electronic absorption and emission spectra, excited state lifetime, quantum yield of fluorescence. Also the dipole moment of electronic transition, the length of attenuation and Oscillator strength of electronic transition from So →S1 have been detected. The dyes with different pumping power were pumped by 3rd harmonic Nd:YAG pulsed laser 8ns pulse duration, with a repetition rate at (10Hz). Good Photo stability of compound 1 and 2 were obtained that was decreased to 49%, 54% and 46%, 40% of the initial ASE of dyes in sol gel and PMMA respectively, after 55000 pumping pulses at (10 mJ/pulse). The dyes in sol-gel show improved Photo stability compared with those in organic polymeric matrices.