“…In order for these larger crystals to manifest a AFM/ORTH phase transition similar to that seen in the smaller Sn-grown crystal, they were annealed at 500 • C (a temperature similar to the decanting temperature of the Sn-grown samples) (Goldman et al, 2009) for 24 h and then quenched to room temperature. Given previous observations of small shifts in the AFM/ORTH phase transition temperatures of BaFe 2 As 2 samples and of the superconducting transition in doped BaFe 2 As 2 , as well as of sharpenings of their signatures in thermodynamic and transport data, after post-growth thermal treatment (Rotundu et al, 2010;Gofryk et al, 2011;Kim et al, 2012a), it is necessary to undertake a systematic study of the effects of postgrowth thermal treatment of FeAs-grown single crystals of CaFe 2 As 2 . In order to characterize and understand the effects of annealing/quenching, as well as the nature of the low-temperature state, a wide variety of thermodynamic, transport, microscopic, and spectroscopic measurements have been performed .…”