Spatio-temporal photolysis rate profiles of UV254 irradiated toluene

Abstract

The volatile organic compound (VOC) toluene is irradiated with a 254 nm UV source. The studied sample (1 mL) of toluene is equipped in a sealed quartz cuvette and inserted in one of the Michelson interferometer’s arms. During a UV254 irradiation of 1 h, the variation in the toluene’s refractive index profiles are monitored as a movement of Michelson interference fringes. These interferograms are recorded and digitally analyzed to produce their phase map distributions and, hence, reconstructing the refractive index profiles which are expressing the toluene’s photolysis behavior. With increasing the UV254 irradiation time, the toluene’s refractive index profiles exhibit both temporal and spatial decrease due to the production of benzyl radicals and the consequent oxidation of these radicals. The spatio-temporal refractive index and photolysis rate profiles of toluene are reconstructed and discussed.