Electrochemical corrosion behaviors of Sn-9Zn-3Bi-xCr solder in 3.5 wt.% NaCl solution were investigated in this work through potentiodynamic polarization measurements. After electrochemical testing, fracture surfaces were investigated by scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffractometry. The results show that adding a small amount of Cr can improve the corrosion resistance of Sn-9Zn-3Bi-xCr solder. The corrosion potential of Sn-9Zn-3Bi solder is À1.251 V. For Sn-9Zn-3Bi-0.5Cr solder, it is À1.200 V. The corrosion potential increased when raising the Cr content, and the Sn-9Zn-3Bi-0.5Cr solder showed the best corrosion resistance. After polarization, a passivation film covered the surface of the Cr-bearing solders. The higher the Cr content, the more compact the passivation film. Long-term aging worsened the corrosion resistance. After 4 days of aging, the corrosion potential of Sn-9Zn-3Bi solder was À1.254 V. After 9 days, it was À1.268 V.