Extensions of the electrostatic probe technique to situations with negative ions, both theoretical and experimental, are described. Charged particle distributions and the plasma-sheath boundary are discussed in relation to probe measurements. Plasmas with negative ions, their occurrence and interest, particularly situations where the negative ion density becomes comparable to or exceeds the electron density are described. Some data in negative ion containing plasmas are shown and discussed. ( a ) DC discharges O2 (Thompson 1961) 0.01-0.05 20 108 12, O2 (Emeleus and Coulter 1983) 0.1-10 3102 ? SF, (Ogle and Woolsey 1987) 0.1-10 400-700 107-109 SF6/Ar (Picard et a/ 1986) 0.2 10-103 109-1 010 l2 (Doucet 1970) =10-3 -103 109 O2 (Bacal and Doucet 1974) 10-3 >IO 108-109 SF, (Wong er a/ 1975) -10-5 >l03 109 CsCl (Goeler et a/ 1966) ? 10-100 10'~-10'2 Scavenge by SF6, WF,; CsCI, Csl, KCI, K1 (Sheehan and Rynn 1988) ? 20-1 04 109-1 010 ( f ) Diffusion plasma l2 (Amemiya 1988a) 10-2-10-' 103-104 109 (g) Lower ionosphere (D-layer) 0, 02, etc (Rose and Widdel