1996
DOI: 10.1557/jmr.1996.0086
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Space filling by nucleation and growth in chemical vapor deposition of diamond

Abstract: Phase transformations, including chemical vapor deposition (CVD) of diamond, taking place by nucleation and growth are commonly described by Avrami or Johnson-Mehl type models. In order to avoid the restrictions of such models with respect to assumptions concerning nucleation rates and growth velocities, the variation with time of nucleation and growth of diamond particles during the deposition of microwave plasma-assisted CVD was studied. The size distributions obtained from image analysis enabled us to trace… Show more

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Cited by 10 publications
(3 citation statements)
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“…Whereas the virgin surfaces of the samples showed a sharp absorption peak at 1332 cm , corresponding to pure diamond (first order Raman), the laser-cut surfaces showed disordered graphite-like peaks due to the G-band (1580 cm ) and D-band (1350 cm ); see Figure 2 . In the case of the virgin surfaces, the peak at 1430 cm observed in the CVD samples [ 25 , 26 , 27 ], was also clearly observed; see Figure 2 .…”
Section: Resultsmentioning
confidence: 80%
“…Whereas the virgin surfaces of the samples showed a sharp absorption peak at 1332 cm , corresponding to pure diamond (first order Raman), the laser-cut surfaces showed disordered graphite-like peaks due to the G-band (1580 cm ) and D-band (1350 cm ); see Figure 2 . In the case of the virgin surfaces, the peak at 1430 cm observed in the CVD samples [ 25 , 26 , 27 ], was also clearly observed; see Figure 2 .…”
Section: Resultsmentioning
confidence: 80%
“…In case of the untreated CVD samples surfaces the peak at 1430 cm −1 , known for CVD samples [19][20][21], is also clearly observed.…”
Section: B Ramanmentioning
confidence: 96%
“…After cutting, a polishing on the cut face was performed. The laser beam with the 87 specified parameters, was focused right on the surface of the sample to burn part of the for CVD samples [19][20][21], is also clearly observed.…”
mentioning
confidence: 95%