The diode emission system with the field emitter as a sphere on cone is presented. The anode is a part of a sphere. The interior of system's domain is contained with different dielectrics. The boundary-value problem for the Laplace's equation is solved in the spherical coordinates.Field electron emitter (FEE) as sphere on cone occur is used in vacuum electronic devices [1]. FEEs can be fabricated by coating a metallic or a carbon emitter with a layers of dielectric materials [2].In this work the axially-symmetrical diode emission system with the field emitter as sphere on cone is presented. The anode is a part of a sphere. The interior of system's domain is contained with different dielectrics.The problem parameters in the spherical coordinate system: the emitter is presented by the coordinate surfaces -α = α 0 (R 0 < r < R N +1 ) (cone), r = R 0 (0 < α < α 0 ) (spherical emitter's tip ); the anode is represented by coordinate surface -r = R N +1 , (0 < α < α 0 ) (part of a sphere); the boundary coordinate surfaces between the different dielectrics with the permittivity ε i−1 and ε i -r = R i , i = 1, N , (0 < α < α 0 ); the potential of the emitter is assumed to be zero -U (R 0 , α) = 0, U (r, α 0 ) = 0; and the potential distribution at the anode: U (R 1 , α) = f (α) (Fig.1).Let us considered the boundary -value problem for the Laplace's equation(1)The whole region of this diode system is divided in N+1 subregions: R i < r < R i+1 and the potential distribution Figure 1.U (r, α) = U i (r, α) (i = 0, N ) can be presented as:P νn (cos α) -Legendre functions; ν n -the Legendre functions zeros P νn (cos α 0 ) = 0. From the boundary conditions (1) A 0 n = 0, A N +1 n = M −1 n α0 ∫ 0 sin αP νn (cos α) f (α) dα, M n -Legendre function normalization coefficients. The continuity conditions of the potential distributions (2) on the surfaces r = R i (i = 1, N ) is satisfied. The normal 978-1-4799-5772