2007
DOI: 10.1016/j.tsf.2006.02.043
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Space charge distributions of an electric double layer capacitor with carbon nanotubes electrode

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Cited by 35 publications
(16 citation statements)
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“…π electron radicals of the carbon basal planes are also susceptible to electrophilic reactions [26,27], which include HER. Acetylene black (AB), Vulcan, and KB were tested as possible cathode catalysts at a temperature of 150 • C. The I-V characteristics increased in the order of KB > Vulcan > AB ( Figure S1a), which agrees especially well with the order of pore volume and average pore diameter (Table S1 [28,29]) that influences the gas removability and ionomer wettability of the electrode, as reflected by the impedance spectra of the electrolysis cells using these cathodes ( Figure S1b). To examine carbon species with different pore structures, commercially available mesoporous carbon materials (MH, MJ10, 30, and 150) were used in place of carbon blacks.…”
Section: Resultssupporting
confidence: 67%
“…π electron radicals of the carbon basal planes are also susceptible to electrophilic reactions [26,27], which include HER. Acetylene black (AB), Vulcan, and KB were tested as possible cathode catalysts at a temperature of 150 • C. The I-V characteristics increased in the order of KB > Vulcan > AB ( Figure S1a), which agrees especially well with the order of pore volume and average pore diameter (Table S1 [28,29]) that influences the gas removability and ionomer wettability of the electrode, as reflected by the impedance spectra of the electrolysis cells using these cathodes ( Figure S1b). To examine carbon species with different pore structures, commercially available mesoporous carbon materials (MH, MJ10, 30, and 150) were used in place of carbon blacks.…”
Section: Resultssupporting
confidence: 67%
“…The lower capacitance is partially attributed to poor wettability of electrode material, which leads to a lower usable specific surface area for charge storage. 18 As another reason, polarization may reduce charge accumulation of the ions on the double-layer. For these reasons, reducing the polarization of activated carbon by introducing TiO2 nanoparticles has been considered to be an effective approach to improve the capacitance of the double-layer capacitors.…”
Section: Introductionmentioning
confidence: 99%
“…Laboratory-Scale Carbonaceous Active Materials Numerous types of carbons that have been tried as electrodes in EDLCs can be summarized as halloysite templated porous carbon [30], multibranched porous carbon nanofibers [31], nanostructured graphite [32], bamboo-based activated carbon [33], woven carbon cloth [34], CNTs [35], nanostructured mesoporous carbon [36], CNT/felt composite electrode [37], cresolformaldehyde-based carbon aerogel [38], mesoporous carbon composite (carbon nanofibers/porous carbon) [39], porous carbon from thermoplastic and MgO precursors [40], sodium-oleate-modified activated carbon aerogel [41,42], carbon aerogel [43][44][45][46], activated carbonized methylcellulose [47], carbide-derived carbons (CDC) [48][49][50][51] silica MCM-48-templated mesoporous carbon [52], zeolite-templated carbon [53], electrospun activated carbon nanofibers [54], silica MCM-48-and SBA-15-templated mesoporous carbon [55], carbon nanofibers [56], carbon blacks, vegetable/wood-based activated carbons, activated novoloid fibers [57], activated needle coke from coal tar pitch [58], fullerene-soot [59], Nomex-derived activated carbon fibers [60], activated CNTs [61,62], mesoporous carbon spheres [63], pyrolyzed carbons from graphite oxides [64], Ketjenblack/CNTs [65], multiwalled [66][67]…”
Section: Current Collector Working In Aqueous Mediummentioning
confidence: 99%