“…Additionally, the additional weak peak at 2θ = 8.48° can be ascribed to the 110 plane. PXRD shows that the diffraction peaks of the synthesized COF are well matched with the literature, , suggesting that the TMT-TA COF with good crystallinity has been successfully prepared. Further, to verify whether functionalization influences the crystallinity of the TMT-TA COF, the structure of TMT-TA-COOH is also characterized by PXRD (Figure a).…”
In this study, a functionalized vinyl-linked 2D fluorescent
covalent
organic framework (COF) (TMT-TA-COOH) is constructed by post-synthetic
modification (PSM) of a TMT-TA COF, which is composed of trimethyltriazine
(TMT) and terephthalaldehyde (TA). The fluorescent COF (TMT-TA) has
the characteristics of good crystallization and stability, but the
dispersibility in water is poor, which requires further PSM. After
PSM, the obtained TMT-TA-COOH not only exhibits good dispersibility
in water but also displays stronger binding ability to analytes, which
presents high sensitivity for quantitative identification of 5-hydroxytryptamine
(5-HT) and its metabolite 5-hydroxyindole-3-acetic acid (5-HIAA) in
water. Moreover, TMT-TA-COOH can specifically recognize 5-HT in serum
and 5-HIAA in urine with a fast response, good anti-interference performance,
and real-time visualization, which enables the TMT-TA-COOH to be a
tool for early detection of neurological diseases and biomarkers for
carcinoid tumors. In addition, TMT-TA-COOH is also a good candidate
for latent fingerprint (LFP) identification, which has the characteristics
of high contrast and low background interference. This work not only
provides a promising platform for the sensing application of fluorescent
COFs in aqueous solution but also opens up a new way for the detection
of LFP information.
“…Additionally, the additional weak peak at 2θ = 8.48° can be ascribed to the 110 plane. PXRD shows that the diffraction peaks of the synthesized COF are well matched with the literature, , suggesting that the TMT-TA COF with good crystallinity has been successfully prepared. Further, to verify whether functionalization influences the crystallinity of the TMT-TA COF, the structure of TMT-TA-COOH is also characterized by PXRD (Figure a).…”
In this study, a functionalized vinyl-linked 2D fluorescent
covalent
organic framework (COF) (TMT-TA-COOH) is constructed by post-synthetic
modification (PSM) of a TMT-TA COF, which is composed of trimethyltriazine
(TMT) and terephthalaldehyde (TA). The fluorescent COF (TMT-TA) has
the characteristics of good crystallization and stability, but the
dispersibility in water is poor, which requires further PSM. After
PSM, the obtained TMT-TA-COOH not only exhibits good dispersibility
in water but also displays stronger binding ability to analytes, which
presents high sensitivity for quantitative identification of 5-hydroxytryptamine
(5-HT) and its metabolite 5-hydroxyindole-3-acetic acid (5-HIAA) in
water. Moreover, TMT-TA-COOH can specifically recognize 5-HT in serum
and 5-HIAA in urine with a fast response, good anti-interference performance,
and real-time visualization, which enables the TMT-TA-COOH to be a
tool for early detection of neurological diseases and biomarkers for
carcinoid tumors. In addition, TMT-TA-COOH is also a good candidate
for latent fingerprint (LFP) identification, which has the characteristics
of high contrast and low background interference. This work not only
provides a promising platform for the sensing application of fluorescent
COFs in aqueous solution but also opens up a new way for the detection
of LFP information.
“…This study extended the application of COFs for selective pollutant degradation to a wide range of photocatalytic transformations. Chen et al 94 reported triazine-based sp 2 -carbon conjugated g-C 18N 3– COFs for the efficient photocatalytic degradation of RhB and detection of pH. The prepared COFs had good photocatalytic performance owing to their protonated broadened light absorption region and narrow band gap.…”
Section: Application Of Metal-free Cof-based Photocatalysts In Enviro...mentioning
Covalent organic frameworks (COFs) are an emerging class of multivacancy organic polymer with a large specific surface area, stable pore size, high crystallinity, and good stability. Moreover, the tailorability of...
“…Since COFs were rst reported in 2005, they have attracted much attention as a new star in the polymeric porous organic material community. Compared with traditional porous organic materials, in addition to the characteristics of stable chemical properties, high specic surface area and ordered pore structure, the biggest advantage of COFs lies in the highly tunable and easy functionalization, which can be synthesized by structural design followed by modication of modied COFs, 85,86 COF-metal composites, 87,88 COF-MIP composites, 89,90 COF membranes, [91][92][93] and COF-composite hydrogel materials, 94,95 which give more functions to common COFs (e.g., dualemission ratio uorescence detection, 19,96 visualization detection, 16,39,97 and RGB analysis 54,98 ). These different forms of COFs are suitable for the applications in different application areas (Fig.…”
Covalent organic frameworks (COFs) are a class of porous crystalline materials based on organic building blocks containing light elements such as C, H, O, N and B interconnected by covalent...
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