Soybean Oil Epoxidation Catalyzed by a Functionalized Metal–Organic Framework with Active Dioxo-Molybdenum (VI) Centers

Abstract

In this work, a functionalized gallium metal–organic framework with active dioxo-molybdenum (VI) centers was evaluated as a catalyst in the epoxidation of soybean oil using tert-butyl-hydroperoxide as an oxidizing agent. The influence of the reaction time, temperature, and concentration of the oxidizing agent was studied, and it was demonstrated that the highest epoxide selectivity was obtained at 110 °C after 4 h of reaction (29% conversion and 91% selectivity) using a soybean oil/oxidizing agent ratio of 1/2. The stability of the metal–organic framework was confirmed by infrared spectroscopy, X-ray powder diffraction, thermogravimetric analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy EDS. The stability tests demonstrated that the catalyst could be reused in the catalytic process for the recovery of vegetable oils. Graphical Abstract