Sources and Formation of Atmospheric Nitrate Over China–Indochina Peninsula in Spring: A Perspective From Oxygen and Nitrogen Isotopic Compositions Based on Passive Air Samplers

Abstract

The formation processes and potential sources of particulate nitrate can be revealed by nitrogen (δ15N-NO3−) and oxygen (δ18O-NO3−) isotopes; however, the linkage and comparative information over a large scale is limited. In this work, the feasibility of using quartz wool disk passive air samplers (Pas-QW) to identify and quantify the nitrate concentrations and their isotopic compositions was demonstrated. The results of a simultaneous sampling campaign from March to June showed that the NO3− concentration was largely attributed to the development of the regional economies. The regional distribution of δ15N-NO3− values was due to the source changes. The decreasing trend of δ18O-NO3− values with latitude from south to north was mainly a combination of oxygen isotopic fractionation of the oxidant induced by natural factors and anthropogenic changes in O3 concentrations. Coal combustion (CC) and mobile sources (MS) have a significant contribution to NOx in the typical urban agglomerations, while the high contribution from biomass burning (BB) and biogenic soil emission (BS) was mainly in areas with high natural productivity and intensive agricultural activities. By allowing simultaneous monitoring at multiple sites and over extended periods, passive sampling complements existing techniques for studying nitrate aerosol, and the results can provide a reference for the spatial distribution of its sources and formation in the China–Indochina Peninsula (CICP).

Increase in Agricultural-Derived NHx and Decrease in Coal Combustion-Derived NOx Result in Atmospheric Particulate N–NH4+ Surpassing N–NO3– in the South China Sea

“…This pattern may be linked to frequent land-based agricultural activities in South China and the Indo-China Peninsula (Figure S18) and higher primary productivity along the coast than offshore (Figure S20). Microbial activity in soil, wetlands, and seawater can result in the release of large pulses of NO, especially in environments with relatively high temperatures and humidity. , Under conditions of high natural productivity and intensive agricultural activities, the extensive use of nitrogen fertilizers in cultivated land can also contribute to increased NO x emissions …”

“…Microbial activity in soil, wetlands, and seawater can result in the release of large pulses of NO, especially in environments with relatively high temperatures and humidity. 34,80 Under conditions of high natural productivity and intensive agricultural activities, the extensive use of nitrogen fertilizers in cultivated land can also contribute to increased NO x emissions. 81 3A).…”