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The article contains sections titled: 1. Introduction 2. Ethanolamines 2.1. Properties 2.1.1. Physical Properties 2.1.2. Chemical Properties 2.2. Production 2.3. Quality Specifications 2.4. Uses 2.5. Economic Aspects 3. N ‐Alkylated Ethanolamines 3.1. Properties 3.1.1. Physical Properties 3.1.2. Chemical Properties 3.2. Production 3.3. Quality Specifications 3.4. Uses and Economic Aspects 4. Isopropanolamines 4.1. Properties 4.1.1. Physical Properties 4.1.2. Chemical Properties 4.2. Production 4.3. Quality Specifications 4.4. Uses 5. N ‐Alkylated Propanolamines and 3‐Alkoxypropylamines 5.1. Properties 5.1.1. Physical Properties 5.1.2. Chemical Properties 5.2. Production 5.3. Quality Specifications 5.4. Uses and Economic Aspects 6. Storage and Transportation 7. Environmental Protection 8. Toxicology and Occupational Health 8.1. General Aspects 8.2. Ethanolamines 8.3. N ‐Alkyl‐ und N ‐Arylethanolamines 8.4. Propanolamines
The article contains sections titled: 1. Introduction 2. Ethanolamines 2.1. Properties 2.1.1. Physical Properties 2.1.2. Chemical Properties 2.2. Production 2.3. Quality Specifications 2.4. Uses 2.5. Economic Aspects 3. N ‐Alkylated Ethanolamines 3.1. Properties 3.1.1. Physical Properties 3.1.2. Chemical Properties 3.2. Production 3.3. Quality Specifications 3.4. Uses and Economic Aspects 4. Isopropanolamines 4.1. Properties 4.1.1. Physical Properties 4.1.2. Chemical Properties 4.2. Production 4.3. Quality Specifications 4.4. Uses 5. N ‐Alkylated Propanolamines and 3‐Alkoxypropylamines 5.1. Properties 5.1.1. Physical Properties 5.1.2. Chemical Properties 5.2. Production 5.3. Quality Specifications 5.4. Uses and Economic Aspects 6. Storage and Transportation 7. Environmental Protection 8. Toxicology and Occupational Health 8.1. General Aspects 8.2. Ethanolamines 8.3. N ‐Alkyl‐ und N ‐Arylethanolamines 8.4. Propanolamines
We successfully synthesized hydroxypropylcellulose (HPC) and methylcellulose (MC) in high yields from cellulose in 6 wt % NaOH/4 wt % urea aqueous solutions at 25°C. The cellulose derivatives were characterized with NMR, size exclusion chromatography/laser light scattering, gas chromatography (GC), ultraviolet, and solubility measurements in different solvents. According to the results of solution 13 C NMR and GC, the individual degree of substitution (DS; i.e., the average number of substituted hydroxyl groups in the monomer unit) at C-2 hydroxyl groups was slightly higher than the DS values at C-3 and C-6 hydroxyl groups for HPC and MC. In comparison with traditional systems, NaOH/urea aqueous solutions were proved to be a stable and more homogeneous reaction medium for preparing cellulose ether with a more uniform microstructure. The low limits for the average number of moles of the substituent groups per monomer unit and the DS value of water-soluble HPC were 1.03 and 0.85, respectively. MC (DS ϭ 1.48) had good solubility in both water and organic solvents, and the precipitation point occurred at about 67°C for a 2% (w/v) aqueous solution. In this way, we could provide a simple, pollution-free, and homogeneous aqueous solution system for synthesizing cellulose ethers.
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